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Anomalous addition of trifluoroacetic acid to 2,3-difluorobicyclohepta[2.2.1]diene-2,5

✍ Scribed by V. R. Polishchuk; L. A. Leites; E. I. Mysov; A. F. Aérov; E. M. Kagramanova


Book ID
112424721
Publisher
Springer
Year
1992
Tongue
English
Weight
199 KB
Volume
41
Category
Article
ISSN
1573-9171

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Photoinduced addition of nucleophiles to
✍ Paul G. Gassman; Kurt D. Olson 📂 Article 📅 1983 🏛 Elsevier Science 🌐 French ⚖ 251 KB

The l-cyanonaphthalene photosensitized addition of water and methanol to the cation-radical of bicyclo[2.2.1]hepta-2,5-diene is described. Recently, we demonstrated that nucleophiles could be added across strained carbon-carbon sigma bonds in photosensitized reactions which are readily interpreted