Anodic Reductions. IV. Reduction of Nitrobenzene, Nitrosobenzene, Azoxybenzene and Azobenzene 1
β Scribed by Yang, John Y.; McEwen, William E.; Kleinberg, Jacob
- Book ID
- 118128426
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 562 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Various azohenzenes and azoxy~nzenes were reduced almost quantitatively to the corresponding hydrazohenzenes by sodium dithionite under mild conditions without the formation of aniline derivatives, using dioetyl vioiogen as an electron-transfer catalyst in acetouitrile-water.
The electrochemical reduction of nitrobenzene, axoxybenzene, azobenxene, phenylhydroxylamine and hydrazobenzene was studied at polycrystalline copper and nickel electrodes in neutral and basic aqueous methanolic solutions. Electronation of nitrobenxene, axe-and axoxybenxene was observed by voltammet