Anodic Reactions of Mercury with Halide Ions in Dimethylformamide
β Scribed by GIVEN, P. H.; PEOVER, M. E.
- Book ID
- 109598729
- Publisher
- Nature Publishing Group
- Year
- 1958
- Tongue
- English
- Weight
- 217 KB
- Volume
- 182
- Category
- Article
- ISSN
- 0028-0836
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π SIMILAR VOLUMES
## Abstract The reactivity of the lithium halides in 83.3% pyridineβdimethylformamide changes from Cl^β^ > Br^β^ > I^β^ to Br^β^ > I^β^ to Br^β^ > I^β^ > Cl^β^ with increasing concentration of the salt from 0 to 0.35 M. This behaviour is explained by ion pairing which reduces the concentration of r
The ways in which nucleophiles may react with cation radicals have recently been discussed in terms of the Dewar-Zimmerman rules. 3-6 A nucleophile which adds either slowly or not at all to a cation radical is thought to be forbidden by symmetry properties from undergoing bond-forming orbital over
## Abstract For Abstract see ChemInform Abstract in Full Text.