✦ LIBER ✦

Anodic oxygen evolution reaction at high temperatures in acid solutions at platinum

✍ Scribed by L.B. Kriksunov; L.V. Bunakova; S.E. Zabusova; L.I. Krishtalik

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 604 KB
Volume: 39
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(94)85020-8

No coin nor oath required. For personal study only.

✦ Synopsis

Attstrae-The polarization curves of oxygen evolution and reduction at platinum electrode were obtained in diluted aqueous solutions of sulfuric and perchloric acids in the temperature range 2&325"C. The Tafel slopes of polarization curves of oxygen evolution are practically independent of the temperature in the whole investigated temperature range. The strong dependence of the transfer coeftlcient upon the temperature is discussed in terms of the influence of adsorption of intermediates on the reaction kinetics. At highest temperatures, a rest potential was observed which may correspond to the reversible oxygen potential.

📜 SIMILAR VOLUMES

Oxygen evolution at nickel anodes in con

Oxygen evolution at nickel anodes in concentrated alkaline solution

✍ Marcella Cappadonia; Jiri Divisek; Thomas von der Heyden; Ulrich Stimming 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 406 KB

The oxygen evolution reaction on platinu

The oxygen evolution reaction on platinum, iridium, ruthenium and their alloys at 80°C in acid solutions

✍ M.H. Miles; E.A. Klaus; B.P. Gunn; J.R. Locker; W.E. Serafin; S. Srinivasan 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 549 KB

A&act -Kinetic parameters were determined for the oxygen evolution reaction on 50-50 atom percent alloys of Ru-Ir, Ru-Pt, and Ir-Pt and compared with results obtained using ruthenium, iridium, platinum, and RuO,,TiO, electrodes. The potentiostatic studies were made on oxide covered electrodes at 80°

Electron transfer through thin anodic fi

Electron transfer through thin anodic films in oxygen evolution at Pt electrodes in alkaline solutions

✍ A. Damjanovic 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 628 KB

Oxygen evolution reaction at Rt electrodes in alkaline solutions is characterized by two linear E-log i relationships. At low current densities (cd), the Tafel slope is close to 60 mV, whereas at bigb cd, it is close to 120 mV. The rates at bigb cd are strongly affected by the presence of an anodic

Stability of helical polyamino acids in

Stability of helical polyamino acids in solution at high temperatures

✍ James S. Franzen; John B. Harry; Caroline Bobik 📂 Article 📅 1967 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 514 KB

Optical rotatory dispersion studies have been carried out at, temperatures up to 150°C. on poly(ybenzy1 Lgliitamate) in a-chloronaphthalene and N-methylcaprolactam, and on poly-6-carbobeiixoxy-L-lysine, poly-6-carbobenzoxy-Lo1 nithine, and poly(bg1utamic acid) in N-methylacetamide. The h3offittrYang

Oxygen gas evolution at, and deteriorati

Oxygen gas evolution at, and deterioration of, RuO2/ZrO2-coated titanium anodes at elevated temperature in strong base

✍ L.D. Burke; M. McCarthy 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 557 KB

The influence of the tunnel probability

The influence of the tunnel probability on the anodic oxygen evolution and other redox reactions at oxide covered platinum electrodes

✍ J.W. Schultze; K.J. Vetter 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 886 KB

Potentiostatic and galvanostatic pulse measurements were carried out to investigate the anodic oxygen evolution at platinum electrodes in IN I&SO4 in dependence on the oxide layer thickness d and the electrode potential F. The thickness d (1 .%I0 A) was obtained from cathodic charging curves. Furthe