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Anodic oxidation of phenolic compounds. 4. Scope and mechanism of the anodic intramolecular coupling of phenolic diarylalkanes

✍ Scribed by Palmquist, Ulf; Nilsson, Anders; Parker, Vernon D.; Ronlan, Alvin


Book ID
120894219
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
1024 KB
Volume
98
Category
Article
ISSN
0002-7863

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The electronic structures of a series of phenols, phenoxyl cation radicals and phenoxyl radicals were calculated by the AM1 method. On the basis of the presumed electrochemical reaction, the electronic structure criteria determining the antioxidant activity are discussed. Ionization potentials, abso