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Anodic oxidation of organic nitrogen compounds. Part I. Cyclization of 1-arylmethylenesemicarbazides

✍ Scribed by Hammerich, Ole; Parker, Vernon D.


Book ID
120818251
Publisher
Royal Society of Chemistry
Year
1972
Weight
335 KB
Category
Article
ISSN
1472-7781

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Anodic fluorination of 2-cyano-1-methylpyrrole using Et 3 Nβ€’2HF in an undivided cell provided the corresponding 5-fluoropyrrole and 2,5,5-trifluoro-1-methyl-3-pyrrolin-2-carbonitrile while the use of Et 3 Nβ€’3HF afforded selectively the latter product, which was readily hydrolyzed to isolable 5,5-dif