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Anodic oxidation of mercury in the presence of monocyclic ligands in propylene carbonate

✍ Scribed by C. Boudon; J. P. Gisselbrecht; M. Gross; M. W. Hosseini

Publisher: John Wiley and Sons
Year: 1989
Tongue: English
Weight: 658 KB
Volume: 1
Category: Article
ISSN: 1040-0397
DOI: 10.1002/elan.1140010604

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✦ Synopsis

A series of 12 macrocycles containing 4, 6, or 8 N, S, and 0 heteroatoms (with increasing size from 14 to 24 atoms in the cycle) was studied to ascertain size and heteroatoms effects on the formation and redox characteristics of their mercuric complexes. The concentration dependence o f anodic currents at mercury electrodes in solutions of these ligands led to the determination of the formation constants of the complexes generated according to the following scheme: kfgGflg'+ + ~L J -, ~g ' + + j I 2 s ( t $ & ) ' + 22N6C4 [16], 24N6C5 [I%], and 24N602 [17b].

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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