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Anodic oxidation of cyanide and cyanate ions on a platinum electrode

✍ Scribed by Fusao Kitamura; Machiko Takahashi; Masatoki Ito

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
444 KB
Volume
136
Category
Article
ISSN
0009-2614

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✦ Synopsis

The oxidation processes of cyanide and cyanate ions on a Pt electrode in aqueous and methanol solutions were studied by infrared spectroscopy. In aqueous solution, the cyanide ion was oxidized to cyanate and successively to carbon dioxide. The reaction proceeded on an oxidized platinum surface. In methanol solution, HNCO is the main product during anodization.

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