𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Anodic elimination of sulfur in nonaqueous solvents

✍ Scribed by J.Q. Chambers; P.R. Moses; R.N. Shelton; D.L. Coffen

Publisher
Elsevier Science
Year
1972
Weight
197 KB
Volume
38
Category
Article
ISSN
0022-0728

No coin nor oath required. For personal study only.

✦ Synopsis

Although desulfurization can be effected by a variety of chemical means 1'2 (see ref. 1 for a recent summary), anodic elimination of sulfur is a novel process 3. Sulfoxides and sulfones are the usual anodic oxidation products of sulfides in nonaqueous 4'5 and aqueous 6'7 solutions. Under rigorously nonaqueous conditions, Cottrell and Mann s found sulfonium ions produced in the oxidation of simple aliphatic sulfides. This communication reports on the electrochemical oxidation of two sulfur heterocycles (( 1) and (3)below)in which the oxidative elimination of sulfur is a major anodic pathway. Disulfide coupling products, which were expected by analogy to the well-studied cysteine-cysteine system 9 and others 1Β°'11, were not major products of the preparative scale electrolyses.

πŸ“œ SIMILAR VOLUMES

Study on the reduction species of sulfur
Study on the reduction species of sulfur by alkali metals in nonaqueous solvents
✍ Shin-Ichi Tobishima; Hideo Yamamoto; Minoru Matsuda πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 873 KB

Rechargeable cells with a sulfur cathode, a lithium anode and a nonaqueous electrolyte operating at ambient temperature have been extensively studied as a possible application of sulfur combined with nonaqueous solvent. However, the behavior of the chemical species formed by the reduction of sulfur

99/02596 Manufacture of carbon materials
99/02596 Manufacture of carbon materials for anodes in secondary batteries comprising nonaqueous solvents
πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science βš– 208 KB

06 Electrical power supply and utilization (scientific, technical) increases with increasing sweep rate and reaches up to 90% for Li+ and 65% for C104-ions at a sweep rate of 40 mV s-'. The formation of a passive film decreases the IDE during the first intercalation/de-intercalation cycle. The open

Structural stability of DNA in nonaqueou
Structural stability of DNA in nonaqueous solvents
✍ Gary Bonner; Alexander M. Klibanov πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 98 KB

One of the defining physicochemical features of DNA in aqueous solution is its ability to maintain a double-helical structure and for this structure to undergo a cooperative, heat-induced denaturation (melting). Herein we show that a 21-mer synthetic DNA can form and maintain such a duplex structure