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Annelation of tricarbonyliron complexes of ortho-disubstituted [4]annulenes. Synthesis of tricarbonyliron complexes of derivatives of bicyclo[6.2.0]decapentaene via Wittig cycloolefination

✍ Scribed by Kaplan, Fred A.; Roberts, Bryan W.


Book ID
127141279
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
693 KB
Volume
99
Category
Article
ISSN
0002-7863

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The order of directing ability is modified on complexation, the most remarkable change being the high efficiency of the F-group. The AB system of H-C(4) and H-C(5) of 4 overlaps with a signal associated with 3 (4.61 ppm). When the lithiation was carried out at -40Β°, 7 YO of 4 and 82 % of 3 were for