The NMR relaxation times of the "C(O) nuclei of formanilide, acetanilide, benzamide, benzoic acid, the benzoate anion and glycine were measured for four different magnetic field values, allowing the determination of the contribution of the shielding anisotropy mechanism to the total relaxation rate.
✦ LIBER ✦
Anisotropic Reorientation and Intermolecular Interactions of Sucrose Molecules in Aqueous Solution. A Temperature and Concentration-Dependent 13 C NMR Relaxation Study
✍ Scribed by Baraguey, Carine; Mertens, Dirk; Dölle, Andreas
- Book ID
- 121005773
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 96 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0022-3654
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The cis/trans conformational equilibrium of the two Ac-Pro isomers of the beta-turn model dipeptide [13C]-Ac-L-Pro-D-Ala-NHMe, 98% 13C enriched at the acetyl carbonyl atom, was investigated by the use of variable temperature gradient enhanced 1H-nmr, two-dimensional (2D) 1H,1H nuclear Overhauser eff