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Anisotropic Oxygen Diffusion Properties in Pr 2 NiO 4+δ and Nd 2 NiO 4+δ Single Crystals

✍ Scribed by Bassat, Jean-Marc; Burriel, Mónica; Wahyudi, Olivia; Castaing, Rémi; Ceretti, Monica; Veber, Philippe; Weill, Isabelle; Villesuzanne, Antoine; Grenier, Jean-Claude; Paulus, Werner; Kilner, John A.


Book ID
121413495
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
357 KB
Volume
117
Category
Article
ISSN
1932-7447

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The oxygen permeability and stability of dense Pr 2 NiO 4+δ ceramics have been appraised in comparison with K 2 NiF 4 -type lanthanum nickelate. In oxidizing atmospheres, Pr 2 NiO 4+δ exhibit an extensive oxygen uptake and decomposition into the Ruddlesden-Popper-type Pr 4 Ni 3 O 10 and praseodymium