Anisotropic fluorescence of Michler's ketone in liquid solutions
β Scribed by Wolfgang Liptay; Hans-Joachim Schumann; Frank Petzke
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 406 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
In solutions of Michler's kerone in ethanol at 295 K, the fluorescence is almost completely anisotropic. This phenomenon iscaused by the unusually short lifetime of the excited singlet state due to a short intrinsic lifetime and processes leading to a vary low quantum yield. The abso.r$tion, fluorescence and phosphorescence spectra, their degree of anisotropy and the.values of the quantum yield at 295 K, 203 K and 100 K are reported.
π SIMILAR VOLUMES
Michkr's ketone'sliows phosphorescence from two levelswtich are populated by intersystem crossing from two corrected singbt levels. Th% is indicated by the dependence of phosphoresQace spectra, decay time, and fluorescence-to-phosphorescence intensity ratio on the wavelength of the exciting light.