A red-shift and broadening of the emission of the BIC J-aggregate in glass were observed at low temperatures (4.5 K). To explain the observation a transformation of the excess excitation energy in the bath with disordering of the structure of molecular aggregate is proposed. The characteristic time
Anisotropic distortion of J-aggregates at decreasing temperature
โ Scribed by L. Daehne; A. Endriss; J. Ihringer
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 197 KB
- Volume
- 224
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Temperature-dependent X-ray diffraction exhibits that the J-aggregates in crystals of bis-(dimethylamino)-heptamethinium perchlorate contract unusually strong at low temperature. The intermolecular distance between the dye cations is reduced from 354 pm at room temperature to 336 pm at 30 IC The results are an important due for the explanation of unusual temperature dependence of collective phenomena of J.aggregates.
๐ SIMILAR VOLUMES
The emission lifetime of the carbocyanine BIC J-aggregate decreased with the increase of the temperature in the range 20-60 K. Several mechanisms are proposed to explain the nonradiative relaxation of the J-aggregate observed in glass.
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