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Anisotropic distortion of J-aggregates at decreasing temperature

โœ Scribed by L. Daehne; A. Endriss; J. Ihringer


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
197 KB
Volume
224
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Temperature-dependent X-ray diffraction exhibits that the J-aggregates in crystals of bis-(dimethylamino)-heptamethinium perchlorate contract unusually strong at low temperature. The intermolecular distance between the dye cations is reduced from 354 pm at room temperature to 336 pm at 30 IC The results are an important due for the explanation of unusual temperature dependence of collective phenomena of J.aggregates.


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