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Anisotropic Collective Motion Contributes to Nuclear Spin Relaxation in Crystalline Proteins

✍ Scribed by Lewandowski, Józef R.; Sein, Julien; Blackledge, Martin; Emsley, Lyndon

Book ID
120591493
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
842 KB
Volume
132
Category
Article
ISSN
0002-7863

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✍ T Nilsson; J Kowalewski 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 152 KB

The slow-motion theory of nuclear spin relaxation in paramagnetic low-symmetry complexes is generalized to comprise arbitrary values of S. We describe the effects of rhombic symmetry in the static zero-field splitting (ZFS) and allow the principal axis system of the static ZFS tensor to deviate from