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Anion–π, Lone-Pair–π, π–π and Hydrogen-Bonding Interactions in a CuII Complex of 2-Picolinate and Protonated 4,4′-Bipyridine: Crystal Structure and Theoretical Studies

✍ Scribed by Chaitali Biswas; Michael G. B. Drew; Daniel Escudero; Antonio Frontera; Ashutosh Ghosh


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
961 KB
Volume
2009
Category
Article
ISSN
1434-1948

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The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ