Anionic synthesis of poly(methylmethacrylate)-poly(4-vinylpyridine) diblock copolymers in the presence of LiCl

✍ Scribed by Nihan Nugay; Claude Hosotte; Turgut Nugay; Gerard Riess

• Publisher: Elsevier Science
• Year: 1994
• Tongue: English
• Weight: 288 KB
• Volume: 30
• Category: Article
• ISSN: 0014-3057
• DOI: 10.1016/0014-3057(94)90257-7

✦ Synopsis

Poly(methylmethacrylate)-poly(4-vinylpyridine) diblock copolymers were synthesized by sequential anionic polymerization, l,l-diphenyl-3-methylpentyllithium was used as initiator and LiCI was added to the system as ligand to modify both initiator and active chain end in order to avoid side reactions. The products were characterized by IH-NMR spectroscopy, size exclusion chromatography and differential scanning calorimetry. The block copolymers show narrow molecular weight distribution and microphase separation as indicated by the presence of two glass transition temperatures. Block copolymer formation was verified by micellization in different solvents. Also, 4-vinylpyridine block can be completely quaternized with methyl iodide as indicated by IH-NMR and FTIR spectroscopies.