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Anionic polymerization of masked disilenes. Regioselective synthesis of monomers, structures of polymers and mechanism of initiation for polysilylenes of the type (R1R2SiSiMe2)n

โœ Scribed by Kenkichi Sakamoto; Masaru Yoshida; Hideki Sakurai


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
618 KB
Volume
35
Category
Article
ISSN
0032-3861

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โœ Anja Loose; William S. Sheldrick ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 205 KB ๐Ÿ‘ 2 views

Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115ยฑ130 ยฐC affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ยดx H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6ยฑ anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4ยฑ species. Similar re