## Abstract The influence of the reaction conditions (time, temperature, concentrations of the monomer, and the initiator) on the amount and composition of the oligomers and high molecular products formed during the heterogeneous anionic polymerization of ϵ‐caprolactone was investigated. The polyme
Anionic polymerization of lactones initiated by alkali graphitides. III. Polymerization of δ-valerolactone initiated by KC24
✍ Scribed by Rashkov, Iliya Bl. ;Gitsov, Ivan
- Publisher
- John Wiley and Sons
- Year
- 1984
- Weight
- 342 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0360-6376
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## Abstract The initiation mechanism of the anionic polymerization of ϵ‐caprolactone (ϵ‐CL) under the action of the potassium graphitide KC~24~ was studied by ^1^H‐NMR spectroscopy of low molecular weight products of the polymerization. On the basis of the experimental results, the assumption was m
## Abstract The influence of methyl substituent on the mechanism of the ring‐opening polymerization of β‐lactones initiated by alkali metal alkoxides is discussed. Attention has been paid to the effect of the substituent position in the monomer molecule on the ring‐opening mechanism, the 3,3‐dimeth