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Anionic polymerisation of methyl methacrylate with complex initiator system

✍ Scribed by Turgut Nugay; Nihan Nugay; Robert Jérôme

Publisher
Springer
Year
2002
Tongue
English
Weight
92 KB
Volume
48
Category
Article
ISSN
0170-0839

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## Abstract Methyl methacrylate (MMA) was polymerized by thiophenol without oxidants. Hydroquinone had no effect on the polymerization, indicating that the polymerization proceeded via a non‐radical process. Since other monomers with an __x__,β‐unsaturated carbonyl group polymerized similarly, the

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A simple alkyl lithium initiator (sBuLi) complexed with LiCl (10 molar equiv.) has been used to initiate the anionic polymerization of various methacrylic monomers, i.e. methyl methacrylate (MMA), tert-butyl methacrylate (tBuMA), glycidyl methacrylate (GMA), and dimethyl amino ethyl methacrylate (DM