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Anionic Phosphane − A New Ligand with a Phosphane and a Weakly Coordinating Heteroborate Moiety

✍ Scribed by Benno Ronig; Herbert Schulze; Ingo Pantenburg; Lars Wesemann

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
181 KB
Volume
2005
Category
Article
ISSN
1434-1948

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✍ José A. Camerano; Miguel A. Casado; Miguel A. Ciriano; Cristina Tejel; Luis A. O 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB

## Abstract Although the pentacoordinated complex [Ir{(allyl)B(CH~2~PPh~2~)(pz)~2~}(cod)] (1; pz=pyrazolyl, cod=1,5‐cyclooctadiene), isolated from the reaction of [{Ir(μ‐Cl)(cod)}~2~] with [Li(tmen)][B(allyl)(CH~2~PPh~2~)‐ (pz)~2~] (tmen=__N__,__N__,__N__′,__N__′‐tetramethylethane‐1,2‐diamine), sho