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Anionic Metal–Organic Frameworks of Bismuth Benzenedicarboxylates: Synthesis, Structure and Ligand-Sensitized Photoluminescence

✍ Scribed by A. Thirumurugan; Anthony K. Cheetham


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
669 KB
Volume
2010
Category
Article
ISSN
1434-1948

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## Abstract Two novel coordination polymers with a 3D pillared‐layer framework, [M^II^(Tdc)(4,4′‐Bpy)]__~n~__ [M = Fe (**1**), Co (**2**); Tdc = thiophene‐2,5‐dicarboxylate; 4,4′‐Bpy = 4,4′‐bipyridine), have been hydrothermally synthesised and structurally characterised. A simultaneous reduction of