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Anionic Ligand Effect on the Nature of Epoxidizing Intermediates in Iron Porphyrin Complex-Catalyzed Epoxidation Reactions

✍ Scribed by Nam, Wonwoo; Jin, Sook Won; Lim, Mi Hee; Ryu, Ju Yeon; Kim, Cheal


Book ID
127123515
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
69 KB
Volume
41
Category
Article
ISSN
0020-1669

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## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford