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Anionic and cationic polymerization of norbornadiene in hydrocarbon

✍ Scribed by Nazan (Kasap) Tunoglu; Nurettin Balcioglu

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
28 KB
Volume
20
Category
Article
ISSN
1022-1336

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✦ Synopsis

Norbornadiene (NBD) has been successfully polymerized in benzene solvent in high yield (up to 100%) using AlCl 3 as initiator. Anionic polymerization of the same compound was achieved using butyllithium as initiator. According to the IR and NMR data, both polymers have a 2,6-disubstituted nortricyclene structure. The cationic polymerization gave an amorphous polymer; the anionic polymerization resulted in the formation of a crystalline product showing higher stability.

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