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Anionic 1,4-Silyl Migration in (2-(Trimethylsilyl)phenyl)phosphonium Methylides

โœ Scribed by Kawachi, Atsushi; Yoshioka, Takahiro; Yamamoto, Yohsuke


Book ID
126770572
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
81 KB
Volume
25
Category
Article
ISSN
0276-7333

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Pressure effects on cation migration in
โœ Masamichi Kasahara; Yoshimi Sueishi; Shunzo Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 122 KB

Pressure effects on the two-site jumping of sodium and potassium cations in a 2,5-di-tert-butyl-1,4-benzoquinone ion pair have been studied using a high-pressure EPR technique. The rate constants of the intramolecular and intermolecular migrations for Na ฯฉ and K ฯฉ were determined from an EPR spectra