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Anion-π interactions in five-membered rings: a combined crystallographic and ab initio study

✍ Scribed by Carolina Garau; Antonio Frontera; David Quiñonero; Pau Ballester; Antonio Costa; Pere M Deyà

Book ID
108107839
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
302 KB
Volume
382
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES

A Theoretical Study of Anion–π Interacti
A Theoretical Study of Anion–π Interactions in Seven-Membered Rings
✍ David Quiñonero; Antonio Frontera; Daniel Escudero; Pablo Ballester; Antonio Cos 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 410 KB

## Abstract Several complexes of tropylium (**1**) with anions are optimized at the RI‐MP2(full)/6‐31++G\*\* level of theory. This binding unit can interact very favorably with anions, and it combines the strength of the electrostatic interaction with the directionality of the anion–π interaction.