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Anion radicals in the reaction of substituted 2,6-dinitroanisoles with potassium methoxide

โœ Scribed by V. F. Starichenko; V. A. Ryabinin; S. M. Shein

Book ID
112437866
Publisher
Springer
Year
1976
Tongue
English
Weight
571 KB
Volume
25
Category
Article
ISSN
1573-9171

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Aromatic nucleophilic substitution VIII.
Aromatic nucleophilic substitution VIII. Stopped-flow kinetics of the transient 1,3-disubstituted anionic ฯƒ complex in the reaction of 1-piperidino-2,4-dinitronaphthalene with potassium methoxide
โœ S. Sekiguchi; T. Takei; T. Aizawa; K. Okada ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Ever since Servis' first observed by NMR spectrometry that in DMSO much faster formation of 1,3\_disubstituted anionic o complex (hereinafter referred to as 1,3-adduct) from 2,4,6\_trinitroanisole (TNA) and 'OCH3 is followed by a much slower attack on the l-position, considerable attention has been