One of the current challenges in the area of supramolecular chemistry involves the preparation of anion receptors with high selectivity for specifically targeted anionic guests. [1] Such systems could have an important role to play in a variety of applications, including sensing, analysis, waste rem
Anion-Induced Synthesis and Combinatorial Selection of Polypyrrolic Macrocycles
โ Scribed by Evgeny A. Katayev; G. Dan Pantos; Marina D. Reshetova; Victor N. Khrustalev; Vincent M. Lynch; Yuri A. Ustynyuk; Jonathan L. Sessler
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 360 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0044-8249
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A macrocyclic neutral ionophore 8 (X = O) capable of binding weakly coordinating anions such as nitrate and bromide in DMSO solution has been designed by a stepwise, deductive approach. The optimum geometrical arrangement of the hydrogen bond donor sites in the target ionophore was determined by DFT