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Anion-Dependent Switching: Dynamically Controlling the Conformation of Hydrogen-Bonded Diphenylacetylenes

โœ Scribed by Ian M. Jones; Prof. Andrew D. Hamilton

Book ID
101544674
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
493 KB
Volume
123
Category
Article
ISSN
0044-8249

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## Abstract Aspartic acid protease model peptides Zโ€“Pheโ€“Asp(COOH)โ€“Thrโ€“Glyโ€“Serโ€“Alaโ€“NHCy (1) and AdCOโ€“Asp(COOH)โ€“Valโ€“Glyโ€“NHBzl (3), and their aspartate anions (NEt~4~)[Zโ€“Pheโ€“Asp(COO^โˆ’^)โ€“Thrโ€“Glyโ€“Serโ€“Alaโ€“NHCy] (2) and (NEt~4~)[AdCOโ€“Asp(COO^โˆ’^)โ€“Valโ€“Glyโ€“NHBzl] (4), having an invariant primary sequence of