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Anion Binding of N-(o-Methoxybenzamido)thioureas: Contribution of the Intramolecular Hydrogen Bond in the N-Benzamide Moiety

✍ Scribed by Qian-Qian Jiang; Burenkhangai Darhkijav; Hao Liu; Fang Wang; Zhao Li; Yun-Bao Jiang


Book ID
112005885
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
345 KB
Volume
5
Category
Article
ISSN
1861-4728

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The energetic effects of the conformational rearrangement of eight Schiff bases, differently chloro-substituted, are discussed on the basis of the results of B3LYP/6-31+G(d,p) calculations. The proton transfer tautomers as well as ''open''-non-hydrogen-bonded forms were considered. It was found, tha