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Anhydrous Lanthanide Schiff Base Complexes and Their Preparation Using Lanthanide Triflate Derived Amides

โœ Scribed by Schuetz, Steven A.; Day, Victor W.; Sommer, Roger D.; Rheingold, Arnold L.; Belot, John A.


Book ID
124082265
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
59 KB
Volume
40
Category
Article
ISSN
0020-1669

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Lanthanide(III) hexaaza macrocyclic Schi
โœ David A Voss Jr.; Lisa A Buttrey-Thomas; Thomas S Janik; Melvyn Rowen Churchill; ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 138 KB

The kinetics of decomposition of several lanthanide(III) hexaaza Schiff-base macrocyclic complexes is examined in aqueous solution. For a given macrocycle, decomposition of the Schiff-base into component amine and carbonyl compound is dependent on which lanthanide ion is used.