Anharmonicity of NH2-stretching vibrations of substituted anilines
โ Scribed by Yumiko Tanaka; Katsunosuke Machida
- Book ID
- 107801685
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 620 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A U(2) algebraic model is presented to describe stretching vibrations of XY n (n ฯญ 2, 3, and 4) systems, where anharmonic interactions between the bond modes are considered. This model in a limit corresponds to an anharmonically coupled local-mode model. As an example, the model for a molecule XY 4
these two theories are.riot exclusive, but'ratber &&. One of the most char&&stid features of the hydrogen-bond X-H.. .Y is the high anharmonic/ty of the stretching vibration vX\_H,W,Y of the H atom in this bond [I] . As a consequence of this anharrnonicity the c&responding infrared spectrum of the v