Anharmonicity in Polyatomic Molecules. The CH-Stretching Overtone Spectrum of Benzene
โ Scribed by Henry, Bryan R.
- Book ID
- 120044364
- Publisher
- American Institute of Physics
- Year
- 1968
- Tongue
- English
- Weight
- 916 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0021-9606
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๐ SIMILAR VOLUMES
A simple dynamical model is used to calculate the overtone spectra of CH and CD stretch vibrations of C6H6 and C6D6 in both vapour and liquid phases. The quantized version of this model describes the normal-mode character of the first excited states. A semiclassical version describes the local-mode
The second CH stretch overtone of benzene has been studied both experimentally and theoretically. A recent high-resolution opto-thermal experiment showed that the overtone spectrum consists of several absorption bands located in the region between 8730 and 8875 cm-'. In this work, we investigate pos