Dedicated to Prof. Ch. Tamm on the occasion of his 60th birthday (12.4.83) ## Summary (-)-1-Camphanoyloxyacrylonitrile (= (-)-1 -cyanovinyl camphanate; 1) obtained from the commercially available ( -)-camphanoyl chloride and 2-0x0propiononitrile added to furan at 20" in the presence of CU(BF,)~.
Anharmonic skeletal deformation in bicyclo[2.2.1]hept-2-ene and 7-oxabicyclo[2.2.1]heptane
β Scribed by R.P. Carlile; T.L. Smithson; H. Wieser
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 553 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Radical addition to 7βoxabicylco[2.2.1]heptβ5βenβ2βone (1) was examined from a regiochemical point of view, and despite the small electronic anisotropy of the double bond, electrophilic radicals were found to add preferentially at C(5) with selectivities of up to 5:1. We also report the
a Values are for individual samples. During the test, one could observe particles of the disintegrated tablet forming a ring at the bottom of the fabricated flask (Fig. 3). It is not likely that one would use the type of dissolution vessel shown in Fig. 2 when the other two types are commercially