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Anharmonic force constants of acetylene. Cubic and quartic force constants of acetylene; calculations with a general quartic force field and an empirical anharmonic potential function

โœ Scribed by I. Suzuki; John Overend


Book ID
113372180
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
847 KB
Volume
25
Category
Article
ISSN
1386-1425

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A harmonic oscillator with time-dependent force constant when perturbed by a weak static quartic anharmonicity ti4, 1 small, is shown to generate new features in the dynamics. For weak coupling, both time-dependent perturbation theoretical analysis and near-exact numerical calculations predict that