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Angular overlap model analysis of the D2d crystal field effect in uranium (4+) compounds

✍ Scribed by Z. Gajek; S. Hubert; J.C. Krupa


Book ID
113314716
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
186 KB
Volume
76-77
Category
Article
ISSN
0304-8853

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Crystal field strength: Angular overlap
✍ M. Faucher; D. Garcia; C.K. JΓΈrgensen πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 390 KB

An expression for the crystal field strength is defined in terms of one-electron energies and crystal field parameters. The relative contribution of kinetic energy and Coulombic interaction in ligand field effects is analyzed. The angular overlap model is applied to 11 rareearth or rareearthdoped co