Angleresolved photoemission with synchrotron radiation has been applied to the study of adsorbed ftis of cytosine on Cu ( 110). Using dipole selection rules, we established that in the monolayer the molecules adsorb with the molecular plane perpendicular to the su&ce while in multilayer films only a
โฆ LIBER โฆ
Angle-resolved photoemission from uracil and thymine adsorbed on Cu(110)
โ Scribed by M.L.M. Rocco; R. Dudde; K.-H. Frank; E.-E. Koch
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 390 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Angle-resolved photoelectron spectra taken with synchrotron radiation are presented for monolayers of uracil and thymine adsorbed on Cu( 110). Applying dipole selection rules within the molecular C, symmetry the a' and a" symmetry species have been experimentally determined in the photoeleclron spectra. The valence orbital assignments are compared to MO calculations. In the monolayer regime the uracil and thymine molecules are found to adsorb with their molecular plane perpendxular to the Cu( 110) surface.
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