✦ LIBER ✦
Anchimer beschleunigte Homolysen, V. Thermische und Fluoridionen-katalysierte Umlagerungen von Benzyl)-[9-(trimethylgermyl)-9-fluorenyl]-ether
✍ Scribed by Reetz, Manfred T. ;Maaroufi, Azzedine ;Greif, Norbert
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1980
- Tongue
- English
- Weight
- 213 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0009-2940
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✦ Synopsis
Anchimerically Enhanced Homolyses, V. Fluoride Ion Catalysed Rearrangements of Benzyl 9‐(Trimethylgermyl)‐9‐fluorenyl Ether
The thermal rearrangement (homolysis) of the germanium compound 1d into 4d is considerably slower than that of the analogous Si compound 1c. Thus, a correlation is suggested between the velocity of the rearrangement and the strength of the new bond to oxygen. The rearrangement 1d→4d is also induced by fluoride ions at room temperature.