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Anatase as a cathode material in lithium—organic electrolyte rechargeable batteries

✍ Scribed by F. Bonino; L. Busani; M. Lazzari; M. Manstretta; B. Rivolta; B. Scrosati


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
515 KB
Volume
6
Category
Article
ISSN
0378-7753

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✦ Synopsis


A preliminary investigation of anatase, TiOe, as a positive electrode material in secondary lithium-organic electrolyte batteries is reported.

Up to 0.6 lithium equivalents can react with 1 mole of TiOs. However, optimum cycling behaviour is obtained for regimes involving compositions between 0.15 and 0.45 Li/TiOa mole ratio.

Under these conditions, prolonged cycling at 0.25 -0.5 mA cm-2 gives satisfactory results.

*Zinc oxide is added to improve the photostability, while phosphorus and potassium oxides are relevant for the particle size.


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