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Analyzing TREF data by stockmayer's bivariate distribution

✍ Scribed by João B. P. Soares; Archie E. Hamielec

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 823 KB
Volume: 4
Category: Article
ISSN: 1022-1344
DOI: 10.1002/mats.1995.040040206

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The Stockmayer bivariate distribution is used to qualitatively and quantitatively interpret TREF (temperature rising elution fractionation) spectra of polyolefins made by multiple site type catalysts. TREF spectra simulated by the proposed method can adequately fit experimental TREF data presented in the literature and can be used to help understand the mechanism of TREF separation and the nature of multiple site types catalysts.

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