A numerical algorithm for solving the Ornstein-Zernike \((O Z)\) integral equation of statistical mechanics is described for the class of fluids composed of molecules with axially symmetric interactions. Since the O7 equation is a monlinear second-kind Frodholm oquation whoso ker feature for the cla
Analytical solution of the Ornstein-Zernike equation with the mean spherical closure for a nematic phase
β Scribed by M.F. Holovko; T.G. Sokolovska
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 903 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0167-7322
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β¦ Synopsis
We propose an analytical method for the calculation of the pair correlation functions and the single-particle distribution function in nematics by the self-consistent solution of the Ornstein-Zernike and Lovett equations. The solution for a model of spherical particles with the long-range anisotropic interactions is obtained in the mean spherical approximation. It is found that in the nematic state the harmonics of the pair correlation function connected with the correlations of the director transverse fluctuations become of long-range type. The structure of the nematic phase is discussed.
π SIMILAR VOLUMES
Tile mean spheriul approximation for a mi..ture of charged hard spheres in a uniform neutralizing background is solved anaIyticzlly\_ The factor correlation functions and the excess thermodynamic properties are explicitly expressed through a single parameter, which can be obtained by solving an alge