Based on the analytical solution of the unsteady heat conduction differential equation, a solution procedure is presented for the inverse unsteady wall heat conduction problem, i.e. for the calculation of the thermal properties of structural elements of existing buildings under real transient conditions, using on-site temperature measurements. Previous procedures, which were based on the finite-difference method, required a considerable number of temperature measurements in space and time within the wall. The advantage of the present analytical procedure is that it requires only two temperature measurements, apart from some information on the outdoor and indoor temperature variations. The two temperature measurements may be taken on the outdoor and indoor wall surfaces at the same time level, or on one of these surfaces at two different time levels. The proposed analytical procedure provides the values of the thermal conductivity and heat capacity of structural elements, and therefore it may be used in practice for expost checking of the materials used by the constructor, or for load calculation when heating or cooling systems are to be installed in old buildings of unknown wall properties. Experimental examples are presented which show that the proposed analytical procedure may be applied in practice with very good accuracy.