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Analytical formula for direction cosines of the Eckart frame of a planar molecule

✍ Scribed by Grigory A. Natanson

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 297 KB
Volume: 121
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)87190-6

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✦ Synopsis

An anatytical Formula is su&ested for cafculaiing direction cosines of the Eckan rrame or a planar molecule. As one application ol' the formula, we give a simple way to rind the matrix swilching oi' the geometrical body-limed axes 01 lhe rormaldehyde molecule lo axes of i!s Erkart frame. Volum'e. 121, number 4.5 CHEMICAL PHYSICS LEl%ERs ..:.lS No~mbcr.1985 with Ri , R f , ye for equilibrium values of R 1, R 3, y respectively. The matrix A is determined by relations (11) with matrix elements Fv calculated by means of (191% (20

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