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Analytical chemistry of unusual oxidation states: The polarography of vanadium(IV) in cyanide medium

✍ Scribed by J.Hernandez Mendez; A.Sanchez Misiego; F.Lucena Conde


Book ID
118992390
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
343 KB
Volume
23
Category
Article
ISSN
0039-9140

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The kinetics of electron transfer in the redox system containing phenylhydrazine (S) and tris(dimethylglyoximato)nickelate(IV), in the presence of catalytic amounts of added CU(&, have been studied in aqueous medium at an ionic strength of 0.25M in the pH range of 6.01-9.06. The kinetics exhibit pse