𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Analytical applications of the o-dianisidine-persulfate reaction: Kinetic determination of silver and cobalt

✍ Scribed by C. Sánchez-Pedreño; M.Hernández Córdoba; P.Viñas López-Pelegrín

Book ID
107828977
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
373 KB
Volume
32
Category
Article
ISSN
0026-265X

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Analytical applications of the reaction
Analytical applications of the reaction of hexacyanoferrate(III) with ascorbic acid : Part V. Determination of silver
✍ L. Erdey; L. Koltai; G. Svehla 📂 Article 📅 1962 🏛 Elsevier Science 🌐 English ⚖ 259 KB

## ERDEY AND RuzAs have described a direct method for the determination of silverl, in which silver ions are reduced to the metal in hot solution with ascorbic acid; the end-point of the titration is detected with variamine blue. However, the simplicity and accuracy of the titration of hexacyanofe

Mechanism and kinetics of the vanadium-c
Mechanism and kinetics of the vanadium-catalyzed o-dianisidine—t-butyl hydroperoxide reaction in non-aqueous media
✍ M. Otto; J. Stach; R. Kirmse 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 705 KB

The vanadium-catalyzed oxidation of o-dianisidine by t-butyl hydroperoxide is studied for the determination of trace vanadium in non-aqueous media. In acetonitrile, vanadium acts as a one-electron mediator between the reductant and oxidant. Mechanistic studies, based on e.p.r. spectrometry and visib