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Analytic expression of the rotation-vibration eigenfunction of any electronic potential of a diatomic molecule

โœ Scribed by Hafez Kobeissi; Mounzer Dagher


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
247 KB
Volume
16
Category
Article
ISSN
0020-7608

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๐Ÿ“œ SIMILAR VOLUMES


A new treatment of the vibrationโ€“Rotatio
โœ Hafez Kobeissi; Mounzer Dagher; Mahmoud Korek; Ahmad Chaalan ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 617 KB

The problem of the determination of the vibration-rotation eigenvalue in diatomic molecules is considered. An eigenvalue equation totally independent from the eigenfunction is written for any potential, analytical or numerical. This equation uses uniquely the vibration-rotation canonical functions;

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Pekeris' solution for vibrational-rotational levels of the Morse potential includes the unphysical domain -a < r < 0 of the internuclear separation, just like Morse's solution for vibrational levels. In this article, the method of confinement in a box is implemented to obtain the vibrational-rotatio