Analysis of volatiles evolved during high-temperature treatment of thermally stable polymers. II. Polybutadiyne

✍ Scribed by Ann E. Mera; Arthur W. Snow

• Publisher: John Wiley and Sons
• Year: 1996
• Tongue: English
• Weight: 560 KB
• Volume: 60
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(19960425)60:4<609::aid-app15>3.0.co;2-u

✦ Synopsis

Polybutadiyne samples were heated at 2O0C/min up to 1200°C in a pyroprobe attached to a gas chromatograph/mass spectrometer (GC/MS). Analysis of the volatiles evolved during heating identified carbon dioxide (adsorbed on polymer surface), methane, ethylene, benzene, toluene, and traces of higher aromatics. Correlations have been made between sample temperature and evolution (onset, maximum, and end temperatures) of each of the five listed volatiles. Average polybutadiyne weight loss at 1200°C was 14 & 2%. Two cure studies were performed in the pyroprobe, and it was shown that both weight loss and volatile evolution were affected. The results were consistent with a higher degree of polymer crosslinking as cure time and temperature increased.