Temperature-modulated calorimetry, TMC, is used to evaluate the temperature region of metastability between crystallization and melting. While crystals like indium can be made to melt practically reversibly during a TMC cycle of low amplitude so that sufficient crystal nuclei remain unmelted, linear
Analysis of transitions of liquid crystals and conformationally disordered crystals by temperature-modulated calorimetry
β Scribed by Wei Chen; Akihiko Toda; Il-Kwon Moon; Bernhard Wunderlich
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 180 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0887-6266
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Temperature-modulated differential scanning calorimetry reveals distinct differences in the kinetics of the low-temperature phase transitions of polytetrafluoroethylene. The triclinic to trigonal transition at 292 K is partially reversible as long it is not complete. As soon as the total sample is c
## Abstract Various laterally fluoroβsubstituted benzonitriles have been prepared containing a __trans__β4β(__n__βalkyl)cyclohexane ring linked to the 4βposition of the benzonitriles either through a methyleneoxy (ο£ΏCH~2~Oβ) or an ethylene (ο£ΏCH~2~CH~2~β) bridge. The bridging group links the benzonit
A comparison of calculated and measured glass transition temperatures of a series of three-component hydrocarbon blends was performed. The blends were prepared as mixtures of an elastomer with different proportions of tackifying resin and oil. Glass transition temperature, T g , was measured by diff