Analysis of the Reorientational Motion of C 60 in Toluene- d 8 : Effects of Solute−Solvent Interactions on Rotational Times in Various Solvents
✍ Scribed by Shang, Xueqin; Issa, Mervat H.; Rodriguez, A. A.
- Book ID
- 127378558
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 41 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
13C spin-lattice relaxation time measurements of buckminsterfullerene were performed in mixtures of protonated and deuterated toluene to determine the magnitude of the intermolecular contribution. Results show that a small but measurable contribution can be attributed to this mechanism. Inclusion of
## Steady -state one-dimensional selective intermolecular carbonarise from carbons d and c since models indicate carbons d 13, proton-1 NOE experiments provide the first experimental evito be less strained than carbon atoms c. Similarly, straindence of specific solute-solvent interactions of fulle