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Analysis of the Kinetic Isotope Effects on Initial Rates in Transient Kinetics †

✍ Scribed by Palfey, Bruce A.; Fagan, Rebecca L.


Book ID
120492776
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
128 KB
Volume
45
Category
Article
ISSN
0006-2960

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## Abstract Multistep hydrogen isotope exchange reactions, such as the íonization of a carbon acid via a carbanion intermediate in a protic solvent, when conducted using an isotopic tracer to monitor the exchange, have the unusual feature that their rate‐determining steps always refer to the transf